Project Description

HGY Series Catalyst FCC catalyst

Applicable Scope

HGY series catalysts are characterized by maximizing gasoline yield and suitable for processing hydrotreated resid or VGO feedstock.

Characteristics

HGY series catalysts can increase yield and RON of gasoline, improve coke selectivity and bottom conversion, as well as metal resistance performance.

Design Philosophy

Aiming at increasing the gasoline yield, the proper arrangement of matrix and/or molecular sieve cracking ability and the structural dimensions of various pores are considered, and acid central density and acid strength of catalyst are adjusted properly. By means of increasing the specific surface of medium pores and large pores of matrix, strengthening the activity of matrix, and using RE exchanged ultra-stable Y-type molecular sieves with enough mesopores as active component, catalyst could achieve required heavy oil cracking capacity. The mesopores of RE exchanged ultra-stable molecular sieve can improve heavy oil macromolecules cracking ability, which is favorable for the diffusion of reaction products and reducing the second cracking of intermediate distillate, allowing catalyst with better gasoline selectivity and coke selectivity.

Property

Table 1 HGY Catalyst Properties

Item Unit Target
Chemical compositions
Al2O3 wt% 46min
Na2O wt% 0.3max
RE2O3 wt% 2.0-3.5
Fe2O3 wt% 0.8max
SO42- wt% 2.0max
MAT (micro activity test) % 73min
Physical properties
Average Bulk Density g/cm3 0.65-0.80
Surface Area m2/g 220min
Pore Volume ml/g 0.33min
Unit cell size Å 24.52-24.62
Loss of Ignition 800 ℃ wt% 13max
Attrition Index %h-1 1.0-5.0
Particle Size Distribution
0-20μm wt% 3max
0-40μm wt % 20max
Average Particle Size μm 65-80

Commercial Reference

The typical commercial results are listed in Tables 2 and 3. The results show that HGY-2000R catalyst has high activity and hydrothermal stability, excellent bottom cracking ability and slurry yield reduction. It also has good coke selectivity.

Table 2 RFCC Feedstock Properties of SK,Korea

Items Typical Analytical Method
Capacity, BPSD 56,000
API 20.4 ASTM D-287
UOP K 11.98
CCR, % 4.3 ASTM D-189
S, % 0.26 ASTM D-4294
N, μg/g 1633 ASTM D-4629
Ni + V, μg/g 7.2 (4 + 3.2) UOP 391
LV%, ℃ ASTM D-1160
5 375
10 413
30 476
50 513

Table 3 Industrial Application Results of HGY-2000R

Items Base Case Case B Case C
Year 7.227.24, 2002 7.318.2, 2002 8.58.7, 2002
Catalyst Base HGY-2000R HGY-2000R
Capacity, barrel/d 52,714 51,469 53,916
Preheating Tempt., ℃ 208 205 204
Riser Tempt., ℃ 519 519 519
2nd Regen. Tempt., ℃ 714 720 713
Make-up rate, t/d 24.6 20.0 20
Recycle rate, t/min 40.60 37.84 41.32
Catalyst/Oil ratio 7.51 7.17 7.52
Yields, %
C3 9.71 10.08 10.94
C4 13.87 14.54 16.02
Light Gasoline 58.66 58.51 59.44
Heavy Gasoline 16.12 15.78 14.56
Total Gasoline 74.78 74.29 74.00
Heavy Diesel 2.14 2.09 1.99
Slurry 8.25 8.12 7.26
Total Liquid 108.76 109.11 110.21
Coke 9.06 9.03 8.93
Feedstock
API 20.77 20.77 21.47
CCR,% 3.93 4.17 3.43
N, μg/g 1,739 1,944 1,697
Ni, μg/g 4.90 5.90 3.37
V, μg/g 6.80 8.23 4.27

Commercial Application

Brand Year Refineries
HGY-2000R
HGY-2003
2002
2004
Refinery in Korea
HGYP
HGY-1J/HGY-2D
HGY-09RD
2003
2006
2010
Refinery in Indonesia
Refinery in Japan
Refinery in Japan
Catalyst #5 2010 Refineries in USA

Products/Grades

HGY-2000R, HGY-2003, HGYP, HGY-1J/HGY-2D,HGY-09RD and Catalyst #5

 

Email: y@yzeolite.com